University:
Massachusetts Institute of Technology
Course:
3.091SC | Introduction to Solid State Chemistry
Academic year:

2020
Views:

432

Pages:

5
Author:

Claire Palmer

3.091 OCW Scholar Self-Assessment Exam Bonding and Molecules Solution Key 2009 Test #1, Problem #3 Answer the following questions about the difluoroiodate ion (IF2+). (a) Draw a 3-dimensional representation of the molecular geometry around the central atom (not simply the Lewis structure). Show all atoms and bonds between them. (b) Name the type of hybrid orbitals that the central atom forms. (c) Name the molecular geometry of the compound. (d) Is IF2+ polar or nonpolar? Explain. (e) Determine the maximum wavelength of electromagnetic radiation capable of breaking the I–F bond. Bond energies(kJ/mol): F–F = 160 I–I = 150 2009 Test #1, Problem #5 On the same graph below, for (1) BeF2; and (2) BeO, sketch the variation in potential energy, Epotential with internuclear separation, r, between a cation and anion pair in each compound. The diagram need not , be drawn to scale; however, you must convey the relative magnitudes of key features. E 0 r 2009 Test #2, Problem #4 (a) Boron exists in the gas state as the dimer, B2. Explain how the fact that B2 is paramagnetic (two unpaired electrons) implies that in this molecule the 2p orbitals must lie at a lower energy than do the 2p. (b) Is the gas molecule, B22, more or less stable than the gas molecule, B2? Explain. - B22 has two more electrons than B2 - these two electrons pair up with the two unpaired electrons in the 2p orbitals, thereby forming two bonds - hence, we expect B22 to be more stable than B2 (c) Aluminum arsenide (AlAs) is a compound semiconductor with a band gap energy, Eg, of 2.3 eV. The value of Eg can be decreased by mixing AlAs with a compound semiconductor that has a smaller band gap energy. Name one such compound semiconductor and justify your choice by making reference to the operative chemical bonding. 2009 Test #2, Problem #5 (a) Which compound do you expect to have the higher boiling point: HF or NH3? Justify your choice with an explanation, using narrative or cartoons or both, that makes reference to the operative chemical bonding. (b) To which does an atom of Ar form a stronger bond: another Ar atom or an atom of Kr? Justify your choice with an explanation, using narrative or cartoons or both, that makes reference to the operative chemical bonding.