Solutions for Lecture 11: Lewis Structures: Breakdown of the Octet Rule | Massachusetts Institute of Technology - Edubirdie

University:
Massachusetts Institute of Technology
Course:
5.111SC | Principles of Chemical Science
Academic year:

2020
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122

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2
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dedalcatechizes

LECTURE 11 1. Write the Lewis structure, including any equivalent energy resonance structures, for the following molecules. (a) xenon trioxide (XeO3) (b) dihydrogen phosphate, PO4H2-1 (c) (AsO4)3(a) Xe O O O (b) 1O O 1O H P O O O H P O O H H (c) 3- O O As O 2. O 3- O O As O O 3- O O As O O 3- O O As O For the following molecules or molecular ions, draw the Lewis structures. (b) XeF3+1 (c) PCl6-1 (d) IF5 (a) AlCl4-1 O 3. Based on Lewis structures, arrange the following molecules in order of increasing bond order (a single bond has a bond order of one, a double bond has a bond order of two, etc.). Circle any molecules that are likely free radicals. (a) C-C bond in C2H2, C2H4, C2H6; (b) Cl-O bond in ClO2-1 and ClO3-1 (Note that there are no O-O bonds.) (a) C2H6 < C2H4 < C2H2 (b) ClO2-1 < ClO3-1

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