University:
San Jose State University
Course:
CHEM 1A | General Chemistry
Academic year:

2022
Views:

10

Pages:

2
Author:

Reed Bruce

Important Name Reactions Wurtz Reaction: 𝑅 − 𝑋 + 2 𝑁 𝑎 + 𝑋 𝑅 → 𝐸 𝑡 ℎ 𝑒 𝑟 𝑅 − 𝑅 + 2 𝑁 𝑎 𝑋 R−X+2Na+XR Ether R−R+2NaX Wurtz-Fittig Reaction: Ar-X + 𝑁 𝑎 + R-X → Ar-R + 𝑁 𝑎 𝑋 Ar-X+Na+R-X→Ar-R+NaX Fittig Reaction: 2 Ar-X + 𝑁 𝑎 → Ar-Ar + 2 𝑁 𝑎 𝑋 2Ar-X+Na→Ar-Ar+2NaX Friedel-Crafts Alkylation Reaction: Ar-H + CH 3 Cl → Anhyd. AlCl 3 Ar-CH 3 + HCl Ar-H+CH 3 Cl Anhyd. AlCl 3 Ar-CH 3 +HCl Friedel-Crafts Acylation Reaction: Ar-H + CH 3 CO-Cl → Anhyd. AlCl 3 Ar-COCH 3 + HCl Ar-H+CH 3 CO-Cl Anhyd. AlCl 3 Ar-COCH 3 +HCl Kolbe's Electrolysis: 2 R-COONa → Electrolysis R-R + 2 𝑁 𝑎 𝑂 𝐻 + 2 𝐶 𝑂 2 + 𝐻 2 ↑ 2R-COONa Electrolysis R-R+2NaOH+2CO 2 +H 2 ↑ Birch Reduction: R − C ≡ C − R’ → Na/Liq.NH 3 R − CH = CH − R’ R−C≡C−R’ Na/Liq.NH 3 R−CH=CH−R’ Clemmensen Reduction: Ph-CO-CH 3 → Zn(Hg)/HCl Ph-CH 2 − CH 3 Ph-CO-CH 3 Zn(Hg)/HCl Ph-CH 2 −CH 3 Wolff-Kishner Reduction: Ar-CO-CH 3 → NH 2 NH 2 / 𝐾 𝑂 𝐻 Ar-CH 2 − CH 3 + N 2 Ar-CO-CH 3 NH 2 NH 2 /KOH Ar-CH 2 −CH 3 +N 2 Swarts Reaction: R-Br or R-Cl → AgF or Hg 2 F 2 R-F R-Br or R-Cl AgF or Hg 2 F 2 R-F Corey-House Synthesis: R-X + R’ − X → 2 Li R − R’ + R − Cu + LiX R-X+R’−X 2Li R−R’+R−Cu+LiX Frankland's Reaction: 2 R-X → Zn R-R + ZnX 2 2R-X Zn R-R+ZnX 2 Sabatier & Senderen Reaction: CH ≡ CH + H 2 → Ni or Pt CH 2 = CH 2 CH≡CH+H 2 Ni or Pt CH 2 =CH 2 Etard Reaction: C 6 H 5 CH 3 → CrO 2 Cl 2 C 6 H 5 CHO C 6 H 5 CH 3 CrO 2 Cl 2 C 6 H 5 CHO

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