Disubstituted Cyclohexanes - Lecture Notes - Edubirdie

University:
York University
Course:
CHEM 1000 | Chemical Structure
Academic year:

2021
Views:

440

Pages:

2
Author:

Niklas

**Disubstituted Cyclohexanes** * Cis and Trans Isomers **1,2-Disubstituted Cyclohexane** * **Cis:** Both substituents on the same side of the ring. * **Trans:** Substituents on opposite sides of the ring. **1,3-Disubstituted Cyclohexane** * **Cis:** Substituents on the same side of the ring. * **Trans:** Substituents on opposite sides of the ring. **1,4-Disubstituted Cyclohexane** * **Cis:** Substituents on the same side of the ring. * **Trans:** Substituents on opposite sides of the ring. **0.1 kcal/mol Higher in Energy** **Polycyclic Systems** * **Bicycles:** * Exo/Endo Face * Rigid **Decaline:** **C10H18** 1. C10 2. Alkane Formula: C10H22 3. ΔH = 22 - 18 = 4 4. 4 x 30 = 120 kJ/mol 5. **90% Unsat.**

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