A Biochemical Claisen-Type Condensation | California State University, Northridge - Edubirdie

University:
California State University, Northridge
Course:
CHEM 334/L | Organic Chemistry II and Lab
Academic year:

2024
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309

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1
Author:

salitrerofuy

Chemistry 334 A Biochemical Claisen-Type Condensation: Acetyl Coenzyme A NH2 O O Me α HS O N H β O Me P N H N O O O- P N O N 5' O- OH O 4' 3' - O N 1' O 2' OH P O Oβ-mercapto- pantothenic acid subunit adenosine-3'-phosphate subunit ethanolamine subunit Coenzyme A = HSCoA O H3 C Acetyl coenzyme A is the corresponding thioester: SCoA Use of acetyl coenzyme A in the citrate cycle: O O- O H3 C SCoA H2 C acetyl CoA - - - SCoA O2 C O O2 C CH2 SCoA CO2 - CO2 O oxaloacetate O HO - O2 C CH2 SCoA CO2 - HO - CH2 CO2 CO2 - O2 C citrate The enzyme, citrate synthase, catalyzes this transformation. + HSCoA

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