Toasting a Gummy Candy

WARNING NOTICE The experiments described in these materials are potentially hazardous. Among other things, the experiments should include the following safety measures: a high level of safety training, special facilities and equipment, the use of proper personal protective equipment, and supervision by appropriate individuals. You bear the sole responsibility, liability, and risk for the implementation of such safety procedures and measures. MIT and Dow shall have no responsibility, liability, or risk for the content or implementation of any of the material presented. TOASTING A GUMMY CANDY A photo taken at MIT 150th Celebration Open House Under the Dome April 30, 2011. Courtesy of Nathan Sanders. Used with permission. Abstract A gummy bear candy is oxidized using KClO3 as the oxidizing agent in a dramatic reaction, which releases a large amount of energy and results in the formation of harmless products KCl, CO2, and H2O. 1 Materials Gummy Bear Candy Potassium chlorate, KClO3 Spatula Explosion Shield Long laboratory tweezers 25mm Heavy-Walled Borosilicate Test Tube Cast Iron Support Stand for Test Tube Clamp Test Tube Clamp Portable Butane Burner or Lab Burner Face shield Safety Potassium chlorate is a strong oxidizer, which could ignite if placed into contact with other materials. It is a known skin, eye, and respiratory tract irritant. Potassium chlorate should always be fresh and weighed on a balance right before using it. It’s a good idea to mass it directly into the test tube you are going to use in this experiment and cover the opening with paraffin wax paper to protect the contents from any contamination. Procedure Mass out approximately 5 grams of potassium chlorate into a 25 x 200 mm heavy walled borosilicate glass test tube. Place some paraffin wax on the open end of the test tube until you are ready to start. Clamp the test tube with a metal test tube clamp as close to the open end as possible. Angle the tube on the cast iron support stand so that it rests at about a 60-65 degree angle. Place the tube behind an explosion shield making sure that the open end is pointing away from any spectators. This reaction should be run in a vented laboratory hood if possible. When ready to begin, put on a face shield and remove the paraffin wax from the test tube. Begin to heat the closed end of the test tube containing the potassium chlorate. Rotate the burner gently with the flame touching the test tube until the potassium chlorate begins to melt around 350 0C. A molten mix of KCl and pure oxygen is released from the KClO3. Continue to heat the KClO3 until it melts and no crystals remain. This is important as leaving any solid KClO3 in the test tube at the start of the reaction may cause it to eject violently from the tube. Once the KClO3 is melted, shut off the burner and use a long pair of laboratory tweezers to pick up one gummy bear. In one quick motion push the gummy candy into the tube. The reaction starts instantly. Discussion The dramatic reaction produces fire and smoke. It almost smells like burnt marshmallows. The gummy bear is sucrose C12H22O11, which is the source of fuel for the reaction. The first reaction produces the molten KCl and a rich oxygen environment. As soon as the gummy sugar is added, it ignites in the rich oxygen environment leading to the combustion reaction producing harmless CO2, H2O and lots of energy. The reaction feeds on itself producing more oxygen until the gummy sugar is consumed. The sequence of reactions is as follows: 2 Disposal The test tube in this reaction is left completely charred and blackened with everything consumed in the reaction. The test tube can be safely disposed of into a laboratory broken glass waste container. References Bob Dayton, Tom Annacone, (1988) Lee Meriwether, Princeton Summer Institute Revised version by Mark Case, CHEM6 TORCH Binder, 1995. 3