Calculate the Molar Mass of Calcium Nitrate

Chemistry Precipitates Handout Background Information: To predict the amount of precipitate that should form, let’s first determine the concentration of each solution and create a balanced chemical equation. Ca(NO3)2 (aqueous) + K2(CO3) (aqueous) ===> Ca(CO)3 (solid) + 2 K (NO3) (aqueous) This equation shows that if we react 1 mole of Calcium Nitrate with 1 mole of Potassium Carbonate (on the left side of the arrow) it will produce 1 mole of Calcium Carbonate and 2 moles of Potassium Nitrate (on the right side of the arrow). Explaining a mole: A mole is simply the number 6.022 X 1023. So, in one mole of Na, sodium, there are 6.022 X 1023 atoms. In a mole of Cl, chloride, there are 6.022 X 1023 atoms. On the periodic table, the molar mass of Na is 28.99 grams so; this means that one mole, 6.022 X 1023 atoms of Na, weighs 28.99 grams. Looking at Cl, its molar mass is 35.45 grams so, one mole, 6.022 X 1023 atoms of Cl, weighs 35.45 grams. Combining these two elements to form NaCl, also known as table salt, results in a molar mass of 28.99 + 35.45 = 63.53 grams. This means that one mole of salt, 6.022 X 1023 atoms, weighs 63.53 grams. If there is one mole of Ca(NO3)2, 164.09 grams, and one mole of K2(CO3), 138.20 grams, then one mole of Ca(CO)3, 100.09 grams, will be produced. This means that if there is 1 mole of each reactant then 1 mole of product will be formed. If there is .5 moles of each reactant than .5 moles of product will be produced and so on. In this experiment, 100mL of each solution are going to be mixed. Let’s say there is a 30% solution of Ca(NO3)2 mixed with a 50% solution of K2(CO3). This means that of the 100mL 30% is Ca(NO3)2 and since 1gm = 1mL, 30% of 100mL is 30 grams of Ca(NO3)2 and 70 grams of water. Now it is possible to find out the number of moles if the mass of Ca(NO3)2 is divided by the amount of Ca(NO3)2 in 1 mole. For this example 30grams/164.09grams per mol = .1828 moles. If the same is done for the K2(CO3) then 50 grams/138.2 grams per mol = .3618 moles. Since the reaction of calcium nitrate and potassium carbonate is 1 mole to 1 mole the most calcium carbonate that can be produced from mixing these two concentrations is .1828 moles. Since there are less moles of calcium nitrate than potassium carbonate the reaction will stop after it has used the .1828 moles that are available and there will be excess potassium carbonate in the solution. There are .1828 moles of calcium carbonate, if multiplied by the amount of grams per mole then we can conclude how much should be produced. Therefore .1828 moles of calcium carbonate times 100.09 grams per mol = 18.29 grams Ca(CO)3. Procedure: 1 Chemistry 1. Be sure to wear safety goggle throughout the experiment. Find the concentrations of each solution from the teacher and record them on the worksheet. Then, calculate the amount of grams and moles of each. Also calculate approximately how much calcium carbonate should be produced. 2. Gather the equipment needed for the lab and be sure everything is clean and dry. 3. Measure the mass of the Petri dish and record the value on the worksheet. 4. Measure 100mL of potassium carbonate with the graduated cylinder and pour into one beaker. 5. Clean and dry the graduated cylinder. Measure 100mL of calcium nitrate and pour into the empty beaker. 6. Carefully pour the potassium carbonate into the calcium nitrate solution. Observe what happens and record observations on the worksheet. Once all of the potassium carbonate has been poured, stir the mixture with a stirring rod. 7. Place the filter paper in the funnel. If the funnel is conical fold the filter paper according to diagram 1 and place in the funnel. Diagram 1 8. Use the ring stand to hold the funnel and position it over the empty beaker. Next pour the mixture into the funnel and allow it to filter out the precipitate. 2 Chemistry 9. Once all of the precipitate has been filtered, use tweezers to take the filter paper and empty the precipitate into the Petri dish. Then, measure the mass and record the value on the worksheet. Perform the calculations to determine how many grams and moles of precipitate have formed. 10. Ask the teacher where to dispose of the waste properly. Clean and dry materials and place in the proper storage area. 11. Complete any remaining calculations and questions and return the worksheet to the teacher. 3