Understanding Nucleophile Reactions - Lecture Notes | Lecture Note - Edubirdie

University:
York University
Course:
CHEM 2021 | Introductory Organic Chemistry II
Academic year:

2023
Views:

343

Pages:

4
Author:

Niklas

Reactions 1. HO-CH2-OH | HO-C-H | HO-C-H | H-C-OH | H-C-OH | CH2OH CH3I + NaH → CH3O-CH2-OH | HO-C-H | HO-C-H | H-C-OH | H-C-OH | CH2OH Williamson ether synthesis Only the primary hydroxyl group undergoes substitution 2. HO-CH2-OH | HO-C-H | HO-C-H | H-C-OH | H-C-OH | CH2OH PhSO2Cl, Pyridine PhLi → Ph-O-CH2-OH | HO-C-H | HO-C-H | H-C-OH | H-C-OH | CH2OH Nucleophilic substitution Only the primary hydroxyl group undergoes substitution 3. HO-CH2-OH | HO-C-H | HO-C-H | H-C-OH | H-C-OH | CH2OH → HO-CH2-OH | HO-C-H | HO-C-H | C=O | H-C-OH | CH2OH HO-CH2-OH | HO-C-H | HO-C-H | C=O | H-C-OH | CH2OH Oxidation Reduces aldehyde to alcohol

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