Diatomic Molecule - Lecture Note - Edubirdie

University:
Santa Fe College
Course:
PHY 2048 | General Physics 1 with Calculus
Academic year:

2024
Views:

99

Pages:

2
Author:

Jabin F.

#Diatomic molecule:- 6(Dof) = 3(Tr)+2(Rot) + 1 (Vib) Non Rigid E = Etr + Erot. + Evib. 9₁ = (91) Tr (91) Rot (Pi) vib. (91) Tr V 13 h = (91) vib. = Btw Classically -1 [Sinh Btwy Quantum mechanically 2 Rotational Rastion function→ E = 1/(1+1)² LI I = MR² 2 g= (21+1) (P1) Rot = Σ (21+1) e 21 k&T -(1+1)² =KST KBT >>1, I = very high 21+1~21, 1+1 vl ($1) Rot 21 e 27 KST Ks7 27 KB7 () 2( 52 STT² IKBT 52

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