Equilibrium Condition Coursework Materials | Santa Fe College - Edubirdie

University:
Santa Fe College
Course:
PHY 2048 | General Physics 1 with Calculus
Academic year:

2024
Views:

331

Pages:

2
Author:

Jabin F.

Equilibrium Conditions Reversible Adiabatic Process: 𝑑 𝑠 = 0 ds=0, Δ 𝑆 = 0 ΔS=0 Entropy 𝑆 S is constant. Irreversible Adiabatic Process: 𝑑 𝑠 > 0 ds>0, Δ 𝑆 > 0 ΔS>0 𝑆 𝑓 − 𝑆 𝑖 > 0 S f −S i >0 (Entropy increases). Adiabatic Process: 𝑑 𝑠 ≥ 0 ds≥0 (Entropy does not decrease). Special Thermodynamic Processes Isothermal-Isochoric Process: 𝑑 𝑇 = 0 dT=0, 𝑑 𝑣 = 0 dv=0 (Temperature and volume are constant). Isothermal-Isobaric Process: 𝑑 𝑇 = 0 dT=0, 𝑑 𝑝 = 0 dp=0 (Temperature and pressure are constant). 𝑑 𝑔 = 𝑣 𝑑 𝑝 − 𝑠 𝑑 𝑇 = 0 dg=vdp−sdT=0 ( 𝑑 𝐺 ) 𝑇 , 𝑃 = 0 (dG) T,P =0 ( 𝑑 𝐺 ) 𝑇 , 𝑃 ≤ 0 (dG) T,P ≤0 Isobaric-Isoentropic Process: 𝑑 𝑝 = 0 dp=0, 𝑑 𝑠 = 0 ds=0 (Pressure and entropy are constant). ( 𝑑 𝐻 ) 𝑃 , 𝑆 = 0 (dH) P,S =0 ( 𝑑 𝐻 ) 𝑃 , 𝑆 ≥ 0 (dH) P,S ≥0 Reversible vs. Irreversible Processes Reversible: ( 𝑑 𝐴 ) 𝑇 , 𝑉 = 0 (dA) T,V =0 Irreversible: ( 𝑑 𝐴 ) 𝑇 , 𝑉 < 0 (dA) T,V <0 𝐴 = 𝑈 − 𝑇 𝑆 A=U−TS 𝐴 𝑓 = 𝑈 − 𝑇 𝑆 𝑓 A f =U−TS f 𝐴 𝑖 = 𝑈 − 𝑇 𝑆 𝑖 A i =U−TS i ( 𝑑 𝐴 ) 𝑇 , 𝑉 ≤ 0 (dA) T,V ≤0

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